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	<title>Applications of Carbon Nanofiber</title>
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	<link>http://sites.duke.edu/chem26hannahnaughton</link>
	<description>CHEM26S Research Class: Dr. Liu&#039;s Lab</description>
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		<title>Introduction/Fabrication of CNF</title>
		<link>http://sites.duke.edu/chem26hannahnaughton/2012/04/18/hello-world/</link>
		<comments>http://sites.duke.edu/chem26hannahnaughton/2012/04/18/hello-world/#comments</comments>
		<pubDate>Wed, 18 Apr 2012 02:50:58 +0000</pubDate>
		<dc:creator>Hannah Naughton</dc:creator>
				<category><![CDATA[Uncategorized]]></category>

		<guid isPermaLink="false">http://sites.duke.edu/chem26hannahnaughton/?p=1</guid>
		<description><![CDATA[In Dr. Liu&#8217;s Nanomaterials lab, the synthesis and applications of Carbon Nanofiber (CNF) were explored. CNF has similar applications to the Carbon Nanotube (CNT), however in comparison it is easier to process/functionalize, due to its larger pore size, and is a lower overall cost. Carbon Nanofiber can act as a supercapacitor, facilitating paper based electronics (film transistors, active matrix displays, [...]]]></description>
				<content:encoded><![CDATA[<p>In Dr. Liu&#8217;s <em>Nanomaterials</em> lab, the synthesis and applications of <span style="text-decoration: underline"><strong>Carbon Nanofiber</strong></span> (CNF) were explored. CNF has similar applications to the <strong><span style="text-decoration: underline">Carbon Nanotube</span></strong> (CNT), however in comparison it is easier to process/functionalize, due to its larger pore size, and is a lower overall cost.</p>

<a href='http://sites.duke.edu/chem26hannahnaughton/2012/04/18/hello-world/cnfthick/' title='CNFTHICK'><img width="150" height="150" src="http://sites.duke.edu/chem26hannahnaughton/files/2012/04/CNFTHICK-150x150.jpg" class="attachment-thumbnail" alt="Most recent CNF synthesized (much larger amount)" /></a>
<a href='http://sites.duke.edu/chem26hannahnaughton/2012/04/18/hello-world/comparison_cnf_cnt/' title='comparison_CNF_CNT'><img width="150" height="150" src="http://sites.duke.edu/chem26hannahnaughton/files/2012/04/comparison_CNF_CNT-150x150.gif" class="attachment-thumbnail" alt="A)Multi-wall CNTs are composed of concentric cylinders of graphene where the basal planes form an inert surface. B)The stacked-cup structure of CNF has exposed graphitic edge planes along its length, providing opportunities for chemical modification of the surface for covalent bonding directly with the matrix." /></a>
<a href='http://sites.duke.edu/chem26hannahnaughton/2012/04/18/hello-world/cnflab-2/' title='CNFlab'><img width="150" height="150" src="http://sites.duke.edu/chem26hannahnaughton/files/2012/04/CNFlab1-150x150.jpg" class="attachment-thumbnail" alt="CNF synthesized in lab 1" /></a>

<div></div>
<p><strong>Carbon Nanofiber</strong> can act as a supercapacitor, facilitating paper based electronics (film transistors, active matrix displays, sensors, and radio-frequency identification devices). To explore these applications, the first step was to synthesize CNF. This was done with the following steps:</p>
<ol>
<li>Carbon fiber, HNO3, Water</li>
<li>Heat to reflux</li>
<li>24 hours</li>
<li>Vacuum filtration</li>
</ol>
<p>The product is shown in the gallery above.</p>
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		<title>Electrochemical Deposition</title>
		<link>http://sites.duke.edu/chem26hannahnaughton/2012/04/17/electrochemical-deposition/</link>
		<comments>http://sites.duke.edu/chem26hannahnaughton/2012/04/17/electrochemical-deposition/#comments</comments>
		<pubDate>Wed, 18 Apr 2012 03:52:31 +0000</pubDate>
		<dc:creator>Hannah Naughton</dc:creator>
				<category><![CDATA[Uncategorized]]></category>

		<guid isPermaLink="false">http://sites.duke.edu/chem26hannahnaughton/?p=14</guid>
		<description><![CDATA[Carbon Nanofiber can act as a supercapacitor, facilitating paper based electronics. To explore this further, we fabricated a supercapacitor using CNT, CNF, and manganese oxides. We then characterized their electrochemical properties in a three electrode system. A procedure modeled after a previous experiment was used (http://www.citeulike.org/article/8188780). CNT (fabricated from previous experiments) was added to CNF. [...]]]></description>
				<content:encoded><![CDATA[<p>Carbon Nanofiber can act as a <strong>supercapacitor</strong>, facilitating paper based electronics.</p>
<p>To explore this further, we fabricated a supercapacitor using CNT, CNF, and manganese oxides. We then characterized their electrochemical properties in a three electrode system. A procedure modeled after a previous experiment was used (<a href="http://www.citeulike.org/article/8188780">http://www.citeulike.org/article/8188780</a>).</p>
<p>CNT (fabricated from previous experiments) was added to CNF. MnO2 was then electrochemically deposited onto the paper. It was calculated that 4.5 mg of MnO2 was deposited on to the paper and the specific capacitance of the paper was 410 F/g. Pictures of the experiment are shown below:</p>

<a href='http://sites.duke.edu/chem26hannahnaughton/2012/04/17/electrochemical-deposition/electrochem/' title='electrochem'><img width="150" height="150" src="http://sites.duke.edu/chem26hannahnaughton/files/2012/04/electrochem-150x150.jpg" class="attachment-thumbnail" alt="3-electrode system" /></a>
<a href='http://sites.duke.edu/chem26hannahnaughton/2012/04/17/electrochemical-deposition/depositionpic/' title='depositionpic'><img width="150" height="150" src="http://sites.duke.edu/chem26hannahnaughton/files/2012/04/depositionpic-150x150.jpg" class="attachment-thumbnail" alt="The CNF/CNT paper after deposition" /></a>
<a href='http://sites.duke.edu/chem26hannahnaughton/2012/04/17/electrochemical-deposition/depositiongraph/' title='depositiongraph'><img width="150" height="150" src="http://sites.duke.edu/chem26hannahnaughton/files/2012/04/depositiongraph-150x150.jpg" class="attachment-thumbnail" alt="Graph of the capacitance of the supercapacitor during deposition" /></a>

<p>Owing to high capacitance, flexibility, robustness, low cost, and low environmental impact, MnO2/CNF-CNT paper supercapacitors can have great potential for diverse flexible energy storage applications.</p>
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		<title>Scanning Electron Microscopy</title>
		<link>http://sites.duke.edu/chem26hannahnaughton/2012/04/17/scanning-electron-microscopy/</link>
		<comments>http://sites.duke.edu/chem26hannahnaughton/2012/04/17/scanning-electron-microscopy/#comments</comments>
		<pubDate>Wed, 18 Apr 2012 03:47:32 +0000</pubDate>
		<dc:creator>Hannah Naughton</dc:creator>
				<category><![CDATA[Uncategorized]]></category>

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		<description><![CDATA[Scanning Electron Microscopy (SEM) was used to view the pore size of the CNF (which was compared to the pore sizes of CNTs). An SEM has a higher resolution than normal microscopes, and images a sample with a high beam of electrons. A comparison of the CNF and CNT images are shown below (the CNT is [...]]]></description>
				<content:encoded><![CDATA[<p><strong>Scanning Electron Microscopy </strong>(SEM) was used to view the pore size of the CNF (which was compared to the pore sizes of CNTs).</p>
<p>An SEM has a higher resolution than normal microscopes, and images a sample with a high beam of electrons.</p>
<p>A comparison of the CNF and CNT images are shown below (the CNT is the smaller image on top).</p>

<a href='http://sites.duke.edu/chem26hannahnaughton/2012/04/17/scanning-electron-microscopy/sem/' title='SEM'><img src="http://sites.duke.edu/chem26hannahnaughton/files/2012/04/SEM.tiff" class="attachment-thumbnail" alt="CNF (notice the larger pore size)" /></a>
<a href='http://sites.duke.edu/chem26hannahnaughton/2012/04/17/scanning-electron-microscopy/cnt/' title='CNT'><img width="150" height="150" src="http://sites.duke.edu/chem26hannahnaughton/files/2012/04/CNT-150x150.jpg" class="attachment-thumbnail" alt="CNT" /></a>

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